Wastewater, cadmium sulfate electrolytic, acid (EC 273-721-3)
Zinc Substances > Zinc UVCBs

 Substance description/characteristics

  1. Name and other identifiers of the substance:

The substance Wastewater, cadmium sulfate electrolytic, acid is a UVCB (origin: inorganic)

Public name: cadmium sulfate bleed solution

Substance identity:
EC number: 273-721-3
EC name: Wastewater, cadmium sulfate electrolytic, acid
CAS number (EC inventory): 69012-21-1
IUPAC name: Electrolytic solution of cadmium sulphate consisting primarily of cadmium sulphate and possibly sulphuric acid
Description: Industrial isolation of the Intermediate Cadmium Sulphate solution (273-721-3) from Cadmium and/or Cadmium compounds leaching, refining or extraction steps, by settling, filtering and other hydrometallurgical processes.Cadmium metal cake or cadmium compound bearing scrap is grinded and leached in order to produce cadmium sulphate solution. Process is carried out in semi-closed leaching tanks, settlers and filter units, with occasional controlled exposure and transfer of the solution for further extraction of cadmium metal or production of cadmium compounds.
Molecular formula:  n.a.
Molecular weight range:  n.a.
Physical state:  liquid at 20°C and 1013 hPa
  1. Souce, process and conclusion
Source Cadmium and/or Cadmium compounds (e.g. Cadmium metal cake, cadmium compound bearing scrap)
Process

Industrial isolation of the Cadmium Sulphate solution (273-721-3) from Cadmium and/or Cadmium compounds leaching, refining or extraction steps, by settling, filtering and other hydrometallurgical processes. Cadmium metal cake or cadmium compound bearing scrap is grinded and leached in order to produce cadmium sulphate solution.
Stockpiling of the primary Cd-material (Cd-metal cake and Cd-bearing recycled scrap) in closed and well ventilated buildings. Feeding of the primary materials into the mixing tank. The leaching reaction with sulphuric acid solutions is kept at the proper temperature and proper pH (~4.2). Filtration of the leach-residue occurs on press-filters, under ventilated hood. Oxidation of some of the present elements may be necessary (i.e. Te > TeO2 or others), followed by another filtration step, if necessary. Further transfer of the Cadmium sulphate solution occurs by pipes or  in specially designed transfer units that prevent any exposure.
Industrial use of the Intermediate Cadmium Sulphate solution (273-721-3) is in the ultimate manufacturing of Cadmium or Cadmium compounds by several metallurgical processes.
The Cadmium sulphate solution is unloaded, potentially mixed with other solutions or reagents and transferred to the reaction vessels through especially designed transfer launders. In hydrometallurgical uses, the mixture is continuously fed to leaching tanks (closed loop of acidic solution, mostly sulphate) used in the production of Cadmium salt. For pyrometallurgical uses, it is first precipitated and transferred as a solid residue to furnaces, i.e. Imperial Smelting Furnace, Blast furnace, distillation device, used in the smelting and extraction of cadmium metal (EC 231-152-8).

Conclusion

Electrolytic solution of cadmium sulphate consisting primarily of cadmium sulphate and possibly sulphuric acid.

  1. Composition

The boundary composition of Wastewater, cadmium sulfate electrolytic, acid is detailed here below.

Elemental composition - boundary:

Core min (% w/w) max (% w/w) typical (% w/w)
Cd 24 48 24,59
Zn 1 22 15,33
S 15 25 20
Na 0 2,9 2,24
Mg 0 1 1
Mn 0 0,8 0,54
Ni 0,1 0,9 0,86
Ca 0 0,3 0,27
Co 0 0,8 0,0005
Tl 0 0,1 0,0005

Mineralogical composition - boundary:

Core min (% w/w) max (% w/w) typical (% w/w)
H2SO4 3,64 6,07 4,86
NiSO4 0,26 2,37 2,27
CdSO4 44,5 89,01 45,6
ZnSO4 2,47 54,3 37,85
NaSO4 0 8,96 6,92
MgSO4 0 4,95 4,95
MnSO4 0 2 1,48
CaSO4 0 10 0,92

4. Classification

The classification is always based on the worst case. For the Wastewater, cadmium sulfate electrolytic, acid, this corresponds to:  
Acute toxicity - oral Acute oral 3
Acute toxicity - inhalation Acute inhal. 2
Skin irritation/corrosion Skin irrit. 2

Serious eye damage / eye irritation

Eye damage 1

Skin sensitisation

Skin sens. 1A

Respiratory sensitisation

Resp. sens. 1B
Mutagenicity Muta. 1B
Carcinogenicity Carc. 1A
Reprotoxicity Repr. 1B
Specific target organ toxicity - repeated: STOT RE 1
Hazards to the aquatic environment (acute/short-term): Aquatic Acute 1
Hazards to the aquatic environment (long-term): Aquatic Chronic 1